Interaction Between Propylene and H2O over Ru-Co/SiO2 -Catalysts of Clusters Type. Communication 2.

G.D. Zakumbaeva, L.B. Shapovalova, A.A. Shurtbaeva

The Institute of Organic Catalysis and Electrochemistry of Ministry of Education and Science of the Republic of Kazakhstan, 142 Kunaev Str., 480100 Almaty, Kazakhstan

Abstract

The interaction between propylene and H2O on Ru-Co/SiO2-catalyst was studied. It was determinedthat the process of the water addition to olefin molecule is carried out with n-propanol, i-propanol andacetone formation. For clarification of the adsorption mechanism of propylene on Ru-Co-clusters the quantum-chemical calculation of interaction between it and Ru-Co, Ru-Ru, Co-Co clusters were carried out.